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Abstract Concerns about family life push some students away from a career in science or lead them away from particular career paths within science. Religion has been shown to have an influence on individuals’ values concerning both family and work. This study uses data from a survey of U.S. graduate students in five science disciplines to estimate a structural equation model examining paths between religiosity, work and family values, and intent to pursue different careers within science. The analysis finds that religiosity is positively associated with the importance placed on family and, through this mediator, is associated with a lower intent to pursue research‐focused academic jobs and higher intent to pursue teaching‐focused academic jobs. We discuss the implications of these findings, particularly as the analysis shows that women and some racial and ethnic minority students are more religious than their male and white peers.